Silver


Silver
/sil"veuhr/, n.
Abba Hillel /ab"euh/, 1893-1963, U.S. rabbi, born in Lithuania.

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I
Metallic chemical element, one of the transition elements, chemical symbol Ag, atomic number 47.

It is a white, lustrous precious metal, valued for its beauty. It is also valued for its electrical conductivity, which is the highest of any metal. Between copper and gold in their common group of the periodic table, it is intermediate between them in many properties. Widely distributed in nature in small amounts, as the native metal and in ores, it is usually recovered as a by-product of copper and lead production. Its use in bullion and coins was overtaken in the 1960s by demand for industrial purposes, especially photography. It is also used in printed electrical circuits, electronic conductors, and contacts. It is the catalyst for converting ethylene to ethylene oxide, the precursor of many organic chemicals. Its use in alloys in sterling (92.5% silver, 7.5% copper) and plated silverware, ornaments, and jewelry remains important; yellow gold used in jewelry is typically 25% silver, and gold dental alloys are about 10% silver. Silver dental fillings are an amalgam of silver and mercury. Silver in compounds, the most important of which is silver nitrate, has valence 1. Its chloride, bromide, and iodide are used in photography and its iodide in cloud seeding.

Dendritic (branching) silver from Ontario

By courtesy of Joseph and Helen Guetterman Collection; photograph, John H. Gerard
II
(as used in expressions)
Silver Horace
Silvers Phil

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Introduction
 chemical element, a white, lustrous metal valued for its decorative beauty and electrical conductivity. Silver is located in Group 11 (Ib) and Period 5 of the periodic table, between copper (Period 4) and gold (Period 6), and its physical and chemical properties are intermediate between those two metals.

Properties, uses, and occurrence
      Together with gold, and the platinum-group metals, silver is one of the so-called precious metals. Because of its comparative scarcity, brilliant white colour, malleability, ductility, and resistance to atmospheric oxidation, silver has long been used in the manufacture of coins, ornaments, and jewelry. Silver has the highest known electrical and thermal conductivity of all metals and is used in fabricating printed electrical circuits and as a vapour-deposited coating for electronic conductors; it is also alloyed with such elements as nickel or palladium for use in electrical contacts. Silver also finds use as a catalyst for its unique ability to convert ethylene to ethylene oxide, which is a precursor of many organic compounds. Silver is one of the noblest—that is, least chemically reactive—of the transition elements.

      Silver ornaments and decorations have been found in royal tombs dating back as far as 4000 BC. It is probable that both gold and silver were used as money by 800 BC in all countries between the Indus and the Nile.

      Silver is widely distributed in nature, but the total amount is quite small when compared with other metals; the metal constitutes 0.05 parts per million of the Earth's crust. Practically all sulfides of lead, copper, and zinc contain some silver. Silver-bearing ores may contain amounts of silver from a trace to several thousand troy ounces per avoirdupois ton, or about 10 percent.

      Unlike gold, silver is present in many naturally occurring minerals. For silver the more important deposits commercially are such compounds as the minerals tetrahedrite and argentite (silver sulfide, Ag2S), which is usually associated with other sulfides such as those of lead and copper, as well as several other sulfides, some of which contain antimony as well. Silver is found generally in lead ores, copper ores, and cobalt arsenide ores and is also frequently associated with gold in nature. Most silver is derived as a by-product from ores that are mined and processed to obtain these other metals. Deposits of native (chemically free, or uncombined) silver are also commercially important.

       SilverBecause the majority of the ores that contain silver also contain the important metals lead, copper, or zinc or a combination of the three, the silver-bearing fraction of these ores is frequently recovered as a by-product of copper and lead production. Pure silver is then recovered from the crude fraction by a combination of smelting and fire- or electrorefining. (For treatment of the recovery and refining of silver, see silver processing.) Silver

      Historically, a major use of silver has been monetary, in the form of reserves of silver bullion and in coins. By the 1960s, however, the demand for silver for industrial purposes, in particular the photographic industry, exceeded the total annual world production.

      Use of the metal for sterling and plated silverware, ornaments, jewelry, and similar products has continued to be important. Alloys of silver with copper are harder, tougher, and more fusible than pure silver and are used for jewelry and coinage. The proportion of silver in these alloys is stated in terms of fineness, which means parts of silver per thousand of the alloy. Sterling silver contains 92.5 percent of silver and 7.5 percent of another metal, usually copper; i.e., it has a fineness of 925. Jewelry silver is an alloy containing 80 percent silver and 20 percent copper (800 fine). Gold dental alloys contain about 75 percent gold and 10 percent silver. The yellow gold that is used in jewelry is composed of 53 percent gold, 25 percent silver, and 22 percent copper. (For treatment of silver's use in ornamental and household objects, see metalwork.)

      Natural silver consists of a mixture of two stable isotopes: (isotope) silver-107 and silver-109. The metal does not react with moist air or dry oxygen but is oxidized superficially by moist ozone. It is quickly tarnished at room temperature by sulfur or hydrogen sulfide. In the molten state, silver can dissolve up to 22 times its volume of oxygen; on solidification, most of the oxygen is expelled, a phenomenon known as the spitting of silver. This can be controlled by the addition of a deoxidant such as charcoal to the molten silver. Silver dissolves readily in nitric acid and in hot concentrated sulfuric acid. The metal will also dissolve in oxidizing acids and in solutions containing cyanide ions in the presence of oxygen or peroxides. Dissolution in cyanide solutions is attributable to the formation of the very stable dicyanoargentate, [Ag(CN)2], ion.

      Like copper, silver has a single s electron outside a completed d shell, but in spite of the similarity in electronic structures and ionization energies there are few close resemblances between silver on the one hand and copper on the other.

Compounds
      For silver the preeminently important oxidation state in all of its ordinary chemistry is the state +1, although the states +2 and +3 are known.

      Silver compounds include such familiar substances as silver chloride (AgCl), silver bromide (AgBr), and silver iodide (AgI). Each of these salts is used extensively in photography (photography, history of). Silver chloride serves as the light-sensitive material in photographic printing papers and, together with silver bromide, in certain films and plates. Despite the relatively high cost of silver chloride no satisfactory substitute has ever been found. The iodide is also used in the manufacture of photographic papers and films, as well as in cloud seeding for artificial rainmaking and in some antiseptics. All three halides are derived from silver nitrate (AgNO3), which is the most important of the inorganic silver salts. Besides these other salts, silver nitrate is also the starting material for the production of the silver cyanide used in silver plating.

atomic number
47
atomic weight
107.868
melting point
960.8° C (1,861.4° F)
boiling point
2,212° C (4,014° F)
specific gravity
10.5 (20° C)
oxidation states
+1, +2
electronic config.
[Kr]4d105s1

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Universalium. 2010.

Synonyms:

Look at other dictionaries:

  • Silver — Sil ver (s[i^]l v[ e]r), n. [OE. silver, selver, seolver, AS. seolfor, siolfur, siolufr, silofr, sylofr; akin to OS. silubar, OFries. selover, D. zilver, LG. sulver, OHG. silabar, silbar, G. silber, Icel. silfr, Sw. silfver, Dan. s[ o]lv, Goth.… …   The Collaborative International Dictionary of English

  • Silver — Sil ver, a. 1. Of or pertaining to silver; made of silver; as, silver leaf; a silver cup. [1913 Webster] 2. Resembling silver. Specifically: (a) Bright; resplendent; white. Silver hair. Shak. [1913 Webster] Others, on silver lakes and rivers,… …   The Collaborative International Dictionary of English

  • Silver — (v. engl. Silber ) bezeichnet Silver (Band), eine Glam Punk Rockband aus Norwegen Silver (Computerspiel), Computerspiel Silver Locus, ein Genort, dessen Produkt eine Rolle in der Melaninsynthese spielt Silver ist der Familienname folgender… …   Deutsch Wikipedia

  • Silver — (plata en ingles) puede referirse a: Apellido Beverly Silver; especialista estadounidense en la historia de las fuerzas del trabajo, el desarrollo y la globalización desde la perspectiva del sistema mundo. Horace Silver. Ron Silver, actor de… …   Wikipedia Español

  • silver — [sil′vər] n. [ME selver < OE seolfer, akin to Ger silber, Goth silubr, prob. a loanword < a non IE source] 1. a soft, white, metallic chemical element that is extremely ductile and malleable, an excellent reflector of light, and the best… …   English World dictionary

  • silver — ► NOUN 1) a precious greyish white metallic chemical element. 2) a shiny grey white colour or appearance like that of silver. 3) coins made from silver or from a metal that resembles silver. 4) silver dishes, containers, or cutlery. 5) household… …   English terms dictionary

  • Silver — Sil ver, v. t. [imp. & p. p. {Silvered}; p. pr. & vb. n. {Silvering}.] 1. To cover with silver; to give a silvery appearance to by applying a metal of a silvery color; as, to silver a pin; to silver a glass mirror plate with an amalgam of tin and …   The Collaborative International Dictionary of English

  • Silver (EP) — Silver EP de Jesu Publicación 11 de abril de 2006 Grabación 2004 2005 Género(s) Post metal Shoegazing Duración 28:39 …   Wikipedia Español

  • silver —    Silver *coins are mentioned in many different contexts. It is not clear how much intrinsic power ascribed to the metal itself some, no doubt, since there is evidence that in Suffolk around 1850 people with fits would beg twelve small silver… …   A Dictionary of English folklore

  • Silver Ao — Silver Ao …   Wikipédia en Français

  • Silver — Sil ver, v. i. To acquire a silvery color. [R.] [1913 Webster] The eastern sky began to silver and shine. L. Wallace. [1913 Webster] …   The Collaborative International Dictionary of English


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