hafnium


hafnium
/haf"nee euhm, hahf"-/, n. Chem.
a gray, toxic metallic element with a high melting point (over 2000°C), found in most zirconium minerals. Symbol: Hf; at. wt.: 178.49; at. no.: 72; sp. gr.: 12.1.
[1923; < NL Hafn(ia) Copenhagen + -IUM]

* * *

 chemical element (atomic number 72), metal of Group 4 (IVb) of the periodic table. It is a ductile metal with a brilliant silvery lustre. The Dutch physicist Dirk Coster and the Hungarian-Swedish chemist George Charles de Hevesy (Hevesy, Georg Charles von) discovered (1923) hafnium in Norwegian and Greenland zircons by analyzing their X-ray spectra. They named the new element for Copenhagen (in New Latin, Hafnia), the city in which it was discovered. Hafnium is dispersed in the Earth's crust to the extent of three parts per million and is invariably found in zirconium minerals up to a few percent compared with zirconium. For example, the minerals zircon, ZrSiO4 (zirconium orthosilicate), and baddeleyite, which is essentially pure zirconium dioxide, ZrO2, generally have a hafnium content that varies from a few tenths of 1 percent to several percent. Altered zircons, like some alvites and cyrtolites, products of residual crystallization, show greater percentages of hafnium (up to 17 percent hafnium oxide in cyrtolite from Rockport, Mass., U.S.). Commercial sources of hafnium-bearing zirconium minerals are found in beach sands and river gravel in the United States (principally Florida), Australia, Brazil, western Africa, and India. Hafnium vapour has been identified in the Sun's atmosphere.

      Ion-exchange and solvent-extraction techniques have supplanted fractional crystallization and distillation as the preferred methods of separating hafnium from zirconium. In the procedure, crude zirconium tetrachloride is dissolved in an aqueous solution of ammonium thiocyanate, and methyl isobutyl ketone is passed countercurrent to the aqueous mixture, with the result that the hafnium tetrachloride is preferentially extracted. The metal itself is prepared by magnesium reduction of hafnium tetrachloride (Kroll process, which is also used for titanium) and by the thermal decomposition of tetraiodide (de Boer–van Arkel process).

      For some purposes separation of the two elements is not important; zirconium containing about 1 percent of hafnium is as acceptable as pure zirconium. In the case of the largest single use of zirconium, however, namely, as a structural and cladding material in atomic reactors, it is essential that the zirconium be essentially free of hafnium, because the usefulness of zirconium in reactors is based on its extremely low absorption cross section for neutrons. Hafnium, on the other hand, has an exceptionally high cross section, and accordingly even slight hafnium contamination nullifies the intrinsic advantage of the zirconium. Because of its high neutron-capture cross section and its excellent mechanical properties, hafnium is used for fabricating nuclear-control rods.

      Hafnium produces a protective film of oxide or nitride upon contact with air and thus has high corrosion resistance. Hafnium is fairly resistant to acids and is best dissolved in hydrofluoric acid, in which procedure the formation of anionic fluoro complexes is important in stabilizing the solution. At normal temperatures hafnium is not particularly reactive but becomes quite reactive with a variety of nonmetals at elevated temperatures. It forms alloys with iron, niobium, tantalum, titanium, and other transition metals. The alloy tantalum hafnium carbide (Ta4HfC5), with a melting point of 4,215° C (7,619° F), is one of the most refractory substances known.

      Hafnium is chemically similar to zirconium. Both transition metals have similar electronic configurations, and their ionic radii (Zr4+, 0.74 Å, and Hf4+, 0.75 Å) and atomic radii (zirconium, 1.45 Å, and hafnium, 1.44 Å) are nearly identical because of the influence of the lanthanide contraction (q.v.). In fact, the chemical behaviour of these two elements is more similar than for any other pair of elements known. Although the chemistry of hafnium has been studied less than that of zirconium, the two are so similar that only very small quantitative differences—for example, in solubilities and volatilities of compounds—would be expected in cases that have not actually been investigated. Natural hafnium is a mixture of six stable isotopes: hafnium-174 (0.2 percent), hafnium-176 (5.2 percent), hafnium-177 (18.6 percent), hafnium-178 (27.1 percent), hafnium-179 (13.7 percent), and hafnium-180 (35.2 percent).

      The most important respect in which hafnium differs from titanium is that lower oxidation states are of minor importance; there are relatively few compounds of hafnium in other than its tetravalent states. (However, a few trivalent compounds are known.) The increased size of the atoms makes the oxides more basic and the aqueous chemistry somewhat more extensive and permits the attainment of coordination numbers 7 and, quite frequently, 8 in a number of hafnium compounds.

atomic number
72
atomic weight
178.49
melting point
2,227° C (4,041° F)
boiling point
4,603° C (8,317° F)
specific gravity
13.31 (20° C)
oxidation state
+4
electronic config.
[Xe]4f145d26s2

* * *


Universalium. 2010.

Look at other dictionaries:

  • Hafnium — Lutécium ← Hafnium → Tantale Zr …   Wikipédia en Français

  • hafnium — [ afnjɔm ] n. m. • 1923; du danois (Køben)havn « Copenhague », lieu de découverte, et suff. ium ♦ Chim. Élément atomique (Hf; no at. 72; m. at. 178,5), métal très brillant, ductile, de la même colonne que le titane et le zirconium. hafnium n. m …   Encyclopédie Universelle

  • Hafnium — kommer af det latinske Hafinia som betyder København. I 1923 Blev det opdaget af D. Coster G. von Hevesey, ved hjælp af røngent spektroskop analyse. Man havde allerede inden opdagelsen forudsat Hafniums exsistensen i adskillige mineraler.… …   Danske encyklopædi

  • hafnium — haf ni*um (h[a^]f n[=e]*[u^]m or h[aum]f n[=e]*[u^]m), n. A metallic element of atomic number 72 present together with zirconium to the extent of 1% to 5% in zirconium minerals. It is a poisonous, ductile metal with a brilliant silver luster, has …   The Collaborative International Dictionary of English

  • *hafnium — ● hafnium nom masculin (de Hafnia, ancien nom latin de Copenhague) Métal rare, analogue au zirconium. (Élément n° 72 de symbole Hf et de masse atomique 178,49.) …   Encyclopédie Universelle

  • hafnium — Symbol: Hf Atomic number: 72 Atomic weight: 178.49 Silvery lustrous metallic transition element. Used in tungsten alloys in filaments and electrodes, also acts as a neutron absorber. First reported by Urbain in 1911, existence was finally… …   Elements of periodic system

  • hafnium — (n.) rare element, 1923, Modern Latin, from Hafnia, Medieval Latin form of Dan. Havn harbor, the usual pre 1400 name of COPENHAGEN (Cf. Copenhagen), Denmark, where it was discovered by physicist Dirk Coster (1889 1950) and chemist George de… …   Etymology dictionary

  • hafnium — [haf′nē əm] n. [ModL: so named (1923) by D. Coster (1889 1950), Du chemist, and G. C. de Hevesy ( c. 1889 1966), Hung chemist, after Hafnia, Latinized name of Dan København, COPENHAGEN, where it was discovered + IUM] a metallic chemical element… …   English World dictionary

  • Hafnium — lutetium ← hafnium → tantalum Zr ↑ Hf ↓ Rf …   Wikipedia

  • Hafnium — Eigenschaften …   Deutsch Wikipedia


Share the article and excerpts

Direct link
Do a right-click on the link above
and select “Copy Link”

We are using cookies for the best presentation of our site. Continuing to use this site, you agree with this.