europium

/yoo roh"pee euhm, yeuh-/, n. Chem.

a rare-earth metallic element whose salts are light pink. Symbol: Eu; at. wt.: 151.96; at. no.: 63.

[1900-05; EUROPE + -IUM]

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▪ chemical element

 (Eu), chemical element, rare-earth metal of the lanthanoid series of the periodic table; it is the least dense, softest, and most volatile member of the lanthanoid series. The element was discovered (1896) by Eugène-Anatole Demarçay and named for Europe. One of the least abundant rare earths, it occurs in minute amounts in many rare-earth minerals such as monazite and also in the products of nuclear fission. Europium is usually separated by reducing it to the +2 oxidation state and precipitating it with sulfate ions. The primary use of europium has been for research purposes. Because it readily absorbs thermal neutrons, it may prove to be of use in nuclear-reactor control rods. It has been used as a phosphor activator, as a component of certain electronic materials, and as an agent in the manufacture of fluorescent glass. The metal has been prepared by electrolysis of the fused halides and by reduction of its oxide by lanthanum metal followed by distillation of the europium metal. It quickly reacts in air, oxygen, and water. Both of its naturally occurring isotopes are stable: europium-151 (47.8 percent) and europium-153 (52.2 percent).

      In its predominant oxidation state of +3, europium behaves as a typical rare earth, forming a series of generally pale pink salts. The Eu³⁺ ion is paramagnetic because of the presence of unpaired electrons. Europium possesses the most easily produced and stablest +2 oxidation state of the rare earths. Europium(+3) solutions can be reduced by zinc metal and hydrochloric acid to give Eu²⁺ in solution; the ion is stable in dilute hydrochloric acid if oxygen from the air is excluded. A series of white to pale yellow or green europium(+2) salts are known, such as europium(II) sulfate, chloride, hydroxide, and carbonate. The halides may be prepared by hydrogen reduction of the anhydrous trivalent halides.

atomic number

63

atomic weight

151.965

melting point

822° C

boiling point

1,527° C

specific gravity

5.244 (25° C)

oxidation states

+2, +3

electronic config.

[Xe]4f ⁷5d⁰6s²

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